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Beilstein J. Org. Chem. 2016, 12, 2256–2266, doi:10.3762/bjoc.12.218
Graphical Abstract
Figure 1: The DOE “Top 10” report [2].
Figure 2: Chemical structure of isosorbide and its epimers isomannide and isoidide.
Scheme 1: Conversion of D-sorbitol to isosorbide via twofold dehydration reaction.
Scheme 2: Possible reaction mechanism for the conversion of D-sorbitol to isosorbide.
Scheme 3: Methoxycarbonylation of isosorbide via DMC chemistry.
Scheme 4: Isosorbide homo- and co-polycarbonate via melt polycondensation.
Scheme 5: Synthesis of DMI via DMC chemistry.
Scheme 6: Comparison of the reactivity of isosorbide with other secondary alcohols in methylation reaction. R...
Figure 3: Chemical structure of isosorbide and its epimers isomannide and isoidide.